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In situ visualization of organic fouling and cleaning mechanisms in reverse osmosis and forward osmosis

机译:反渗透和正渗透中有机污垢和清洁机制的原位可视化

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摘要

Fouling models rely on knowledge of foulant accumulation and removal mechanisms. In this study, a foulingvisualization apparatus is developed to elucidate centimeter-scalemechanisms of organic fouling and cleaningin reverse osmosis (RO) and forward osmosis (FO). Alginate is used as a model organic foulant and dyedwith methylene blue, which is shown not to affect fouling or cleaning, and to sufficiently highlight the gelfor visualization at low salinity (up to 1% NaCl). When cleaning by increasing the cross-flow velocity, with orwithout reverse permeation, foulant peels off the membrane in discrete pieces in both RO and FO. Videos ofcleaning show that foulant cake swelling and wrinkling can facilitate gel detachment and removal. Despitetheir effectiveness in slowing fouling, spacers can hinder removal of detached foulant pieces by obstructingtheir path. Finally, photographs point to a new mechanism of internal fouling in FO: vapor formation due to sub-atmospheric pressure within the membrane. Awareness of these mechanisms allows for better modeling of fouling and motivates optimization of swelling-inducing cleaning procedures.
机译:结垢模型依赖于结垢积累和清除机制的知识。在这项研究中,开发了一种结垢可视化设备,以阐明反渗透(RO)和正向渗透(FO)中有机结垢和清洁的厘米级机理。海藻酸盐用作模型有机污垢剂,并用亚甲蓝染色,显示出不影响污垢或清洁的效果,并充分突出了凝胶,可在低盐度(高达1%NaCl)下可视化。当通过增加错流速度进行清洁时,无论有无反向渗透,污垢都会在RO和FO中以离散的形式从膜上剥离。清洁视频显示,结垢的蛋糕膨胀和起皱可促进凝胶的分离和去除。尽管它们在减缓结垢方面是有效的,但是隔离物仍会通过阻塞其路径而阻碍分离出的结垢碎片的去除。最后,照片指出了FO内部结垢的新机制:由于膜内低于大气压而形成蒸汽。对这些机制的意识允许对结垢进行更好的建模,并促使优化溶胀诱导的清洁程序。

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